Product ID:02802, FORMULASHELL PLUS GASOLINE WITH (SUPDAT)
MSDS Date:01/25/1996
FSC:9130
NIIN:00N084607
MSDS Number: CGTND

SHELL OIL CO

HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461;800-424-9300(CHEMTREC)

Info Phone: 713-241-4819

Cage: SHELO

SHELL OIL COMPANY

4320 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

ALKANES, CYCLOALKANES, ALKANES & AROMATIC HYDROCARBONS

Fraction By Weight: MIXTURE

OSHA PEL N/K

ACGIH TLV: N/K

XYLENE (SARA 313) (CERCLA)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 0-25%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL;9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0-25%

OSHA PEL 200 PPM; Z-2

ACGIH TLV: S, 50 PPM; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE (SARA 313) (CERCLA)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 0-4%

OSHA PEL SEE 1910.1028

ACGIH TLV: 10 PPM; A2; 9495

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

HEXANE (N-HEXANE) (CERCLA)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 0-3%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9495

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ETHYL ALCOHOL; (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight:

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9495

BENZENE,1,2,4-TRIMETHYL-; (PSEUDOCUMENE

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 0-5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9495

CYCLOHEXANE (SARA 313) (CERCLA)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: 0-1%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE, ETHYL-; (ETHYL BENZENE) (SARA 313)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 0-3%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125STEL;9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

NAPHTHALENE (SARA 313) (CERCLA)

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: 0-1%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM/15 STEL; 9495

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

THIS PROD MAY BE HARMFUL/FATAL

RTECS: 9999999ZZ

(BRTHG) OF VOMITUS INTO LUNGS MUST BE AVOIDED AS

RTECS: 9999999ZZ

READILY ABSORBED & MAY PRDCE CNS DEPRESS. PRLNG &

RTECS: 9999999ZZ

AS NOTED ABOVE. EARLY TO MOD CNS DEPRESS MAY BE EVID

RTECS: 9999999ZZ

UNCONSCIOUSNESS & DEATH MAY OCCUR. ASPIR PNEUMONITIS

RTECS: 9999999ZZ

(BLUISH SKIN); IN SEV CASES DEATH MAY OCCUR. KIDNEY

RTECS: 9999999ZZ

APPEAR/EDEMA (SWELLING FROM FLUID RETENTION). LIVER

RTECS: 9999999ZZ

(YELLOWISH SKIN COLOR) & SOMETIMES PAIN IN UPPER

RTECS: 9999999ZZ

IF MORE THAN 2.0 ML PER KG HAS BEEN INGESTED &

RTECS: 9999999ZZ

SUPERVISION. KEEP VICTIM'S HEAD BELOW HIPS TO PVNT

RTECS: 9999999ZZ

OR UNCONSCIOUSNESS OCCUR BEFORE EMESIS,

RTECS: 9999999ZZ

CARCINOGENIC. OSHA REGULATED, 29 CFR

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:TOLUENE APPEARS ON THE NAVY LISTING OF
OCCUP CHEM REPROD HAZ. SEEK CONSULTATION FROM APPROP HLTH
PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS
INFO . EYE: BASED ON PROD TEST ING PROD IS IRRIT TO EYES. SKIN:
PRLNG & RPTD LIQ CNTCT CAN CAUSE DEFAT & DRYING OF SKIN RSLTG IN
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE:IARC MONO, SUPP. VOL 7, PG 120,
1987: GROUP 1. NTP 7TH ANNUAL REPORT ON CARCINOGENS, 1994: KNOWN TO
BE (ING 22)
Effects of Overexposure:HLTH HAZ:SKIN IRRIT & DERM. INHAL: THIS PROD MY
CAUSE IRRIT TO NOSE, THROAT & RESP TRACT & ADDITIONALLY, MAY PRDCE
LIVER & KIDNEY DMG. HIGH VAP CONCS MAY PRDCE CNS DEPRESS. PRLNG &
RPTD EXPOS TO BENZE NE MAY CAUSE SERIOUS INJURY TO BLOOD FORMING
ORGANS & IS LINKED TO LATER DEVELOPMENT OF ACUTE MYELOGENOUS (ING
11)
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN, & RESP
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. IMPAIRED
LIVER AND KIDNEY FUNCTION(S) FROM PREEXISTING DISORDERS MAY BE
AGGRAVATED BY EXPOSURE TO THIS PRODUCT.

First Aid:EYE: FLUSH W/H*2O AT LEAST 15 MIN WHILE HOLDING EYELIDS OPEN.
GET MET ATTN. SKIN: FLUSH W/H*2O WHILE REMOVING CONTAMD CLTHG &
SHOES. FOLLOW BY WASHING W/SOAP & H*2O. DO NOT REUSE CLTHG/SHOES
UNTIL CLE ANED. IF IRRIT PERSISTS, GET MED ATTN. INHAL: REMOVE
VICTIM TO FRESH AIR & PROVIDE OXYGEN IF BRTHG IS DFCLT. GIVE ARTF
RESP OF NOT BRTHG. GET MED ATTN. INGEST: DO NOT INDUCE VOMIT. IF
VOMIT (ING 18)

Flash Point Method:TCC
Flash Point:-40F,-40C
Lower Limits:1.3%
Upper Limits:7.6%
Extinguishing Media:USE WATER FOG, FOAM, DRY CHEM/CO*2. DO NOT USE A
DIRECT STREAM OF H*2O. PROD WILL FLOAT & CAN BE REIGNITED ON SURF
H*2O.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
DANGER. EXTREMELY FLAMM. CLEAR FIRE AREAS OF UNPROTECTED PERS &
ISOLATE. DO NOT ENTER CONFINED FIRE (SUPDAT)
Unusual Fire/Explosion Hazard:VAP ARE HVR/AIR ACCUMULATING IN LOW AREAS
& TRAVELING ALONG GROUND AWAY FROM HNDLG SITE. DO NOT WELD,
HEAT/DRILL ON/NEAR CNTNR. HOWEVER, IF EMER (SUPDAT)

Spill Release Procedures:DANGER. EXTREMELY FLAMM. ELIM ALL IGNITION
SOURCES. HNDLG EQUIP MUST BE GROUNDED TO PVNT SPARKING. LRG SPILL:
ISOLATE THE HAZ AREA & DENY ENTRY TO UNNEC PERS. WEAR APPROP NIOSH
APPRVD RESP & PROT CLTH G. FOR MORE SPECIFIC INFO CONTACT NEHC .
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DANGER. EXTREMELY FLAMM. AVOID HEAT,
SPARKS, OPEN FLAMES, INCL PILOT LIGHT, & STRONG OXIDIZING AGENTS.
USE EXPLOSION-PROOOF VENT TO PVNT STARKING.
Other Precautions:HARMFUL OR FATAL IF SWALLOWED. DO NOT SIPHON GASOLINE
BY MOUTH. FOR MORE SPECIFIC INFORMATION CONTACT NEHC .

Respiratory Protection:AVOID BREATHING VAPOR. UNDER CONDITIONS OF
POTENTIAL HIGH EXPOSURE, THE USE OF A NIOSH APPROVED RESPIRATOR IS
RECOMMENDED. PER 29 CFR 1910.134 OR 29 CFR 1910.1028. FOR MORE
SPECIFIC INFORMATION CONTAC T NEHC .
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:NITRILE RUB/POLYINYL ALCOHOL/VITON.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART #: ETHANOL (CONVENTIONAL AND REG). SPEC GRAV:
0.72-0.76 (H*2O=1). VP: 7-14.5 PSI (REID). % VOLAT: 100 (@ 415 DEG.
F). FIRE FIGHT PROC: SPACE. COOL FIRE CNTNRS W/H*2O. EXPLO HAZ:
SITUATIONS REQ DRILLING, ONLY TRAINED EMER PERS SHOULD DRILLING,
ONLY TRAIN EMERGENCY PERSONNEL SHOULD DRILL.

Boiling Pt:B.P. Text:>100F,>38C
Vapor Pres:SUPDAT
Vapor Density:3.5
Spec Gravity:SUPDAT
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BRONZE COLOR; CLEAR AND BRIGHT LIQUID. HYDROCARBON
ODOR.
Percent Volatiles by Volume:SUPDAT

Stability Indicator/Materials to Avoid:YES
AVOID HEAT, PARKS, OPEN FLAMES AND STRONG OXIDIZING AGENTS. PREVENT
VAPOR ACCUMULATION.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER UNIDENTIFIED
ORGANIC COMPOUNDS CAN BE FORMED UPON COMBUSTION.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE & LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.